1. Αποθετήριο Παραδοτέων Υποτρόφων Δράσεων ΕΣΠΑ Τριτοβάθμιας Εκπαίδευσης 2017-2023
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Τύπος:	Άρθρο σε επιστημονικό περιοδικό
Τίτλος:	Traceless directing groups in sustainable metal-catalyzed C–H activation
Συγγραφέας:	[EL] Ζαρκαδούλας, Αθανάσιος[EN] Zarkadoulas, Athanasios [EL] Ζγουλέτα, Ιωάννα[EN] Zgouleta, Ioanna [EL] Τζουράς, Νικόλαος[EN] Tzouras, Nikolaos [EL] Βουγιουκαλάκης, Γεώργιος[EN] Vougioukalakis, Georgios
Ημερομηνία:	27/04/2021
Περίληψη:	Sustainable transformations towards the production of valuable chemicals constantly attract interest, both in terms of academic and applied research. C–H activation has long been scrutinized in this regard, given that it offers a straightforward pathway to prepare compounds of great significance. In this context, directing groups (DG) have paved the way for chemical transformations that had not been achievable using traditional reactions. Few steps, high yields, selectivity and activation of inert substrates are some of the invaluable assets of directed catalysis. Additionally, the employment of traceless directing groups (TDG) greatly improves and simplifies this strategy, enabling the realization of multi-step reactions in one-pot, cascade procedures. Cheap, abundant, readily available transition metal salts and complexes can catalyze a plethora of reactions employing TDGs, usually under low catalyst loadings—rarely under stoichiometric amounts, leading in greater atom economy and milder conditions with increased yields and step-economy. This review article summarizes all the work done on TDG-assisted catalysis with manganese, iron, cobalt, nickel, or copper catalysts, and discusses the structure-activity relationships observed, by presenting the catalytic pathways and range of transformations reported thus far.
Γλώσσα:	Αγγλικά
Σελίδες:	37
DOI:	10.3390/catal11050554
EISSN:	2073-4344
Θεματική κατηγορία:	[EL] Χημεία, διεπιστημονική προσέγγιση[EN] Chemistry, interdisciplinary
Λέξεις-κλειδιά:	homogeneous catalysis; organometallic catalysis; sustainable metal catalysis; C–H activation; Organic Synthesis; manganese; iron; cobalt; nickel; Copper
Κάτοχος πνευματικών δικαιωμάτων:	© 2021 by the authors. Licensee MDPI, Basel, Switzerland.
Όροι και προϋποθέσεις δικαιωμάτων:	This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https:// creativecommons.org/licenses/by/ 4.0/).
Ηλεκτρονική διεύθυνση του τεκμηρίου στον εκδότη:	https://www.mdpi.com/2073-4344/11/5/554
Ηλεκτρονική διεύθυνση περιοδικού:	https://www.mdpi.com/journal/catalysts
Τίτλος πηγής δημοσίευσης:	Catalysts
Τεύχος:	5
Τόμος:	11
Σελίδες τεκμηρίου (στην πηγή):	Article no 554
Σημειώσεις:	This research was co-financed by Greece and the European Union (European Social Fund—ESF) through the Operational Programme «Human Resources Development, Education and Lifelong Learning 2014–2020» in the context of the project “Sustainable catalytic systems in Organic Synthesis” (MIS: 5047938).
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